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New method for the synthesis of phosphonic and phosphinic esters and their thio analogs Communication 15. Addition of phenyl-and alkyl-phosphonous esters to methacrylic and acrylic esters

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The methyl, ethyl, isopropyl, isobutyl, hexyl, heptyl, octyl, and nonyl partial esters of phenylphosphonous acid have been synthesized.

  2. 2.

    It has been shown that, in presence of alkali-metal alkoxides, partial esters of phenylphosphonous and alkylphosphonous acids readily add on to methacrylic and acrylic esters.

  3. 3.

    Various esters of (2-alkoxycarbonylethyl)phenyl-, (2 alkoxycarbonylethyl)ethyl-, (2-alkoxycarbonylpropyl)phenyl-, and (2-alkoxycarbonylpropyl)ethyl-phosphinic acids have been synthesized.

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Literature cited

  1. A.N. Pudovik, J. Gen. Chem., 22, 467, (1952).

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  2. G. Kosolapoff, J. Am. Chem. Soc. 72, 4292 (1950).

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  3. B.A. Arbuzov and N.I. Rizpolozhensky, Bull. Acad. Sci. U.S.S.R., Div. Chem. Sci., No. 5, 956, (1952).

  4. A. N. Pudovik, Proc.Acad. Sci. U.S.S.R., 73, 499 (1950).

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Authors and Affiliations

  1. A. E. Arbuzov Chemical Institute of the Kazan Affiliated Institute of the U.S.S.R. Academy of Sciences, USSR

    A. N. Pudovik & D. Kh. Yarmukhametova

Authors
  1. A. N. Pudovik
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  2. D. Kh. Yarmukhametova
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Pudovik, A.N., Yarmukhametova, D.K. New method for the synthesis of phosphonic and phosphinic esters and their thio analogs Communication 15. Addition of phenyl-and alkyl-phosphonous esters to methacrylic and acrylic esters. Russ Chem Bull 1, 803–806 (1952). https://doi.org/10.1007/BF01198867

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  • DOI: https://doi.org/10.1007/BF01198867

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