Skip to main content
SpringerLink
Log in

Certain alkylphosphonothionic, alkylphosphonoselenonic, dialkylphosphinic, and alkylphosphonous esters, and the mechanism of addition to alkylphosphonous esters

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Certain alkylphosphonous esters have been synthesized.

  2. 2.

    Their ability to combine with halogen, sulfur, and selenium and to undergo oxidation has been demonstrated.

  3. 3.

    The ability of ethylphosphonous dichloride to unite readily with sulfur in presence of a catalyst has been demonstrated.

  4. 4.

    The greater ease with which the esters RP(OR)2, as compared with the esters P(OR)3, and ArP(OR)2, undergo addition and isomerization reactions has been demonstrated, and an explanation has been given for this phenomenon.

  5. 5.

    Esters of dialkylphosphinic and alkylphosphonoselonic acids have been synthesized for the first time.

  6. 6.

    Methods have been given for the synthesis of alkylphosphonothionic acids.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. E. Arbuzov, “Catalysis Phenomena in the Reactions of Certain Phosphorus Compounds”, Kazan, 1914.

  2. R. B. Fox, J. Am. Chem. Soc. 72, 4147 (1950).

    Google Scholar 

  3. M. Kharasch, E. Jensen, S. Weinhause, J. Org. Chem. 14, 429, (1951).

    Google Scholar 

  4. F. Guichard, Ber. 32, 1572 (1899).

    Google Scholar 

  5. A. Hofmann, Ber. 4, 605 (1871).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. S. M. Kirov Kazan Chemico-Tehnical Institute, USSR

    A. I. Razumov, O. A. Mukhacheva &  Sim-Do-Khen

Authors
  1. A. I. Razumov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. A. Mukhacheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sim-Do-Khen
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Razumov, A.I., Mukhacheva, O.A. & Sim-Do-Khen Certain alkylphosphonothionic, alkylphosphonoselenonic, dialkylphosphinic, and alkylphosphonous esters, and the mechanism of addition to alkylphosphonous esters. Russ Chem Bull 1, 797–802 (1952). https://doi.org/10.1007/BF01198866

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01198866

Keywords

Search

Navigation