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Crystal and molecular structure of bis(N,N-diethyldithiocarbamato)palladium(II)

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Abstract

The crystal and molecular structure of bis(N,N-diethyldithiocarbamato)palladium(II), Pd(S2CN(C2H5)2)2, has been determined by a three-dimensional X-ray analysis. The compound crystallizes in the tetragonal space groupP42/n with unit cell dimensionsa = 16·439(8) Å andc = 6·247(3) Å. The crystals are isomorphous with bis(N,N-diethyldithiocarbamato)platinum(II). Intensities were obtained with an automatic diffractometer. The structural parameters were refined by least-squares methods to a conventionalR factor of 0·038 for 600 non-zero observed reflections. The palladium is in planar coordination with four sulphur atoms, the two non-equivalent Pd-S bond lengths being 2·317(3) and 2·315(3) Å.

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Authors and Affiliations

  1. Crystallography Laboratory, University of Nijmegen, Nijmegen, The Netherlands

    P. T. Beurskens, J. A. Cras, Th. W. Hummelink & J. H. Noordik

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  1. P. T. Beurskens
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  2. J. A. Cras
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  3. Th. W. Hummelink
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  4. J. H. Noordik
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Additional information

The authors are grateful to Mr J. G. M. van Rens for providing the crystals and measuring the unit cell dimensions, to Professor J.J. Steggerda for his continuous interest and to Mr W.P.J.H. Bosman, Mr J.M.M. Smits and Mr J.A.B.C. Wolf for valuable assistance.

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Beurskens, P.T., Cras, J.A., Hummelink, T.W. et al. Crystal and molecular structure of bis(N,N-diethyldithiocarbamato)palladium(II). Journal of Crystal and Molecular Structure 1, 253–257 (1971). https://doi.org/10.1007/BF01198537

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  • DOI: https://doi.org/10.1007/BF01198537

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