Abstract
The crystal structures of two isomeric complex compounds of formula [Cu(Cl)2(NH2NHCONH2)] have been determined by X-ray diffraction methods. The orthorhombic isomer has space groupPna21 and unit cell constants:a = 6·91(1),b = 8·30(1),c = 10·24(1) Å;Z = 4. The monoclinic isomer has space groupP21/c and unit cell constants:a = 6·91(1),b = 8·30(1),c = 11·32(1) Å, β = 117·1(2)°;Z = 4. In both complexes coordination around copper is octahedral, with chains of coordination polyhedra along [100]. In the monoclinic compound, the two semicarbazide molecules, which are present in two adjacent octahedra along the chain, have the oxygen and nitrogen atoms in thetrans configuration, one with respect to the other, and are correlated by a centre of symmetry. In the orthorhombic compound, the two semicarbazide molecules are in thecis configuration and there is no centre of symmetry. In both compounds packing is determined by the NH···Cl and NH···O hydrogen bonds which join the chains together.
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The authors are indebted to Mr M. Lanfranchi who prepared the compounds and to Dr A. Immirzi who made abailable his computer programs.
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Chiesi Villa, A., Gaetani Manfredotti, A., Nardelli, M. et al. Crystal and molecular structures of the orthorhombic and monoclinic isomers of catena-di-μ-chloro-semicarbazidecopper(II). Journal of Crystal and Molecular Structure 1, 245–251 (1971). https://doi.org/10.1007/BF01198536
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DOI: https://doi.org/10.1007/BF01198536