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Crystal and molecular structure of bis(N,N′-diethyldithiocarbamato)diphenylstannane, C22H30N2S4Sn

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Abstract

Bis(N,N′-diethyldithiocarbamato)diphenylstannane crystallises in the mono-clinic system:a = 14.98(3),b = 9.44(2),c = 18.30(3) Å, β = 90.5(1) °,Z = 4,P21/c. The structure has been solved using visually estimated three-dimensional intensity data collected with a precession camera and MoKα. radiation, and refined by full-matrix least squares toR = 0.08 for 1724 non-zero reflections. The molecule contains two bidentate dithiocarbamato ligands resulting in a distortedcis octahedral geometry around the tin atom; the phenyl groups subtend an angle of 101.4(6) ° at this atom.

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Author notes

  1. Pamela Carr

    Present address: Department of Chemical Sciences, The Hatfield Polytechnic, P.O. Box 109, Hatfield, Hertfordshire, England

Authors and Affiliations

  1. Department of Crystallography, Birkbeck College, Malet St., WC1E 7HX, London, England

    P. F. Lindley & Pamela Carr

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  1. P. F. Lindley
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  2. Pamela Carr
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Lindley, P.F., Carr, P. Crystal and molecular structure of bis(N,N′-diethyldithiocarbamato)diphenylstannane, C22H30N2S4Sn. Journal of Crystal and Molecular Structure 4, 173–185 (1974). https://doi.org/10.1007/BF01197912

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  • DOI: https://doi.org/10.1007/BF01197912

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