Skip to main content
SpringerLink
Log in

Determination of phosphorus in organic compounds by NMR

  • Published:
Microchimica Acta Aims and scope Submit manuscript

Summary

A method is described for the microdetermination of phosphorus by FTNMR in organic compounds containing transition metals. Approximately 10 mg of compound is digested for the determination and 2 mg Cr added as relaxation agent.

Zusammenfassung

Eine Mikromethode zur Bestimmung des Phosphors in organischen, Übergangsmetalle enthaltenden Verbindungen mit Hilfe der Fourier-Transform P31 kernmagnetischen Resonanz wurde beschrieben. Ungefähr 10 mg Substanz werden mit Schwefelsäure-Perchlorsäure aufgeschlossen und 2 mg CrIII werden als Relaxans zugegeben.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Gurley and W. Ritchey, Analyt. Chemistry47, 1444 (1975).

    Google Scholar 

  2. T. Gurley and W. Ritchey, Analyt. Chemistry48, 1137 (1976).

    Google Scholar 

  3. B. Thiault and M. Mersseman, Org. Magn. Resonance7, 575 (1975).

    Google Scholar 

  4. B. Thiault and M. Mersseman, Org. Magn. Resonance8, 28 (1976).

    Google Scholar 

  5. T. Moeller (ed.), Inorganic Synthesis5, 130 (1957).

  6. F. Ehrenberger and S. Gorbach, Methoden der organischen Elementar- und Spurenanalyse, Weinheim: Verlag Chemie. 1973. pp. 359, 389.

    Google Scholar 

  7. T. S. Ma and J. D. McKinley, Jr., Mikrochim. Acta [Wien]1953, 4.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Maryland, 20742, College Park, MD, USA

    F. Kasler & M. Tierney

Authors
  1. F. Kasler
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Tierney
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kasler, F., Tierney, M. Determination of phosphorus in organic compounds by NMR. Mikrochim Acta 70, 411–422 (1978). https://doi.org/10.1007/BF01197093

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01197093

Keywords

Search

Navigation