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The Guerbet reaction applied to diodone

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Summary

The Guerbet reaction is a test for the presence of an aromatic nucleus. Diodone acid is found to give a positive test. The reaction has been followed step by step, the reaction products being separated by thin-layer chromatography and identified by mass spectrometry. The loss of the acetic acid group during the nitration step is remarkable.

Zusammenfassung

Die Reaktion von Guerbet dient zum Nachweis eines aromatischen Kernes. Diodonsäure gibt diesen Nachweis. Stufe für Stufe dieser Reaktion wurde verfolgt, wobei die Reaktionsprodukte dünnschicht-chromatographisch getrennt und massenspektroskopisch identifiziert wurden. Bemerkenswert ist der Verlust der Essigsäuregruppe im Verlauf der Nitrierung.

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References

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Authors and Affiliations

  1. Department of Analytical Chemistry and Pharmaceutical Analysis, Gorlaeus Laboratoria, State University, Postbus 9502, 2300, RA Leiden, The Netherlands

    H. A. Dingjan & H. A. Crezée

Authors
  1. H. A. Dingjan
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  2. H. A. Crezée
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Dingjan, H.A., Crezée, H.A. The Guerbet reaction applied to diodone. Mikrochim Acta 70, 395–402 (1978). https://doi.org/10.1007/BF01197091

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  • DOI: https://doi.org/10.1007/BF01197091

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