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An automated titration of phosphine and a first investigation of the application in the determination of organo-phosphorus compounds

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Summary

An acidimetric titration is used to determine phosphine by its reaction with mercury(II) chloride in aqueous medium. About 0.1μmole of P is determined. The titration is checked with phosphine samples, generated from phosphonium iodide, and is in use to study the reductive destruction of phosphorus-containing substances.

Zusammenfassung

Eine acidimetrische Titration wurde zur Bestimmung von Phosphin in wäßriger Lösung nach dessen Reaktion mit Quecksilber(II)chlorid angewendet. Ungefähr 0,1μMol P wurde bestimmt. Das Verfahren wurde mit Phosphin geprüft, das aus Phosphoniumjodid freigesetzt wurde, und findet Anwendung bei dem reduktiven Aufschluß phosphorhältiger Substanzen.

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Authors and Affiliations

  1. Analytical Chemistry Laboratory of the University, Utrecht, The Netherlands

    F. G. Römer, A. J. H. Schimmelpenninck van der Oije & B. Griepink

Authors
  1. F. G. Römer
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  2. A. J. H. Schimmelpenninck van der Oije
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  3. B. Griepink
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Römer, F.G., van der Oije, A.J.H.S. & Griepink, B. An automated titration of phosphine and a first investigation of the application in the determination of organo-phosphorus compounds. Mikrochim Acta 69, 185–191 (1978). https://doi.org/10.1007/BF01196992

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  • DOI: https://doi.org/10.1007/BF01196992

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