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Catalytic hydrocondensation of carbon monoxide with olefins Communication 11. Behavior of 2-methyl-2-butene aid 2,3-dimethyl-2 butene in the catalytic hydrocondensation reaction

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The behavior of 2-methyl-2-butene and 2,3-diniethyl-2-butene in the reaction of hydrocondensation with carbon monoxide has been investigated.

  2. 2.

    It has been found that 2-methyl-2-butene enters into the hydrocondensation reaction to an extent of only 5–6%, and undergoes hydrogenation to 2-methylbutane to the extent of 30–35%.

  3. 3.

    Under the conditions of the hydrocondensation reaction, 2,3-dimethyl-2-butene is hydrogenated to 2,3-dimethylbutane to the extent of about 50%. About 10% of it undergoes the hydrocondensation reaction.

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Literature cited

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Authors and Affiliations

  1. Institute of Organic Chemistry of the USSR Academy of Sciences, USSR

    Ya. T. Eidus, K. V. Puzitsky & A. P. Meshcheryakov

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  1. Ya. T. Eidus
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  2. K. V. Puzitsky
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  3. A. P. Meshcheryakov
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Eidus, Y.T., Puzitsky, K.V. & Meshcheryakov, A.P. Catalytic hydrocondensation of carbon monoxide with olefins Communication 11. Behavior of 2-methyl-2-butene aid 2,3-dimethyl-2 butene in the catalytic hydrocondensation reaction. Russ Chem Bull 3, 123–126 (1954). https://doi.org/10.1007/BF01195433

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  • DOI: https://doi.org/10.1007/BF01195433

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