Abstract
The crystal and molecular structures of the title compounds CuCl·C8H14 and AgNO3·C8H14, have been determined by single-crystal X-ray diffraction techniques, and refined by full-matrix least squares. Both compounds crystallize in the orthorhombic space groupPbca witha=6.191(7),b=12.456(2),c=23.272(4) Å for CuCl·C8H14, anda=7.383(2),b=9.825(2),c=26.980(5) Å for AgNO3·C8H14;Z=8 in both cases. FinalR factors are 0.047 and 0.029 respectively. The cyclooctene ring has the twist chair-chair (TCC) conformation, with approximateD 2 symmetry, in both compounds, and the torsion angles around the double bonds are −134.2(4) and −137.0(4)° respectively. Slight lengthening of the metal-complexed double bond is attributed to enhanced olefin → metal σ-donation of thetrans bond.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Albinati, A., Meille, S. V., and Carturan, G. (1979) J. Organomet. Chem.183, 269.
Baenziger, N. C., Haight, H. L., and Doyle, J. R. (1964a)Inorg. Chem. 3, 1535.
Baenziger, N. C., Richards, G. F., and Doyle, J. R. (1964b)Inorg. Chem. 3, 1529.
Bischof, P., and Heilbronner, E. (1970)Helv. Chim. Acta 53, 1677.
Boeyens, J. C. A., Denner, L., Orchard, S. W., Rencken, I., and Rose, B. G. (1986)S. Afr. J. Chem. 39, 229.
Cremer, D., and Pople, J. A. (1975)J. Am. Chem. Soc. 97, 1354.
Cope, A. C., and Pawson, B. A. (1965)J. Am. Chem. Soc. 87, 3649.
Deyrup, J. A., and Betkouski, M. (1972).J. Org. Chem. 37, 3561.
Ermer, O. (1981) InAspekte von Kraftfeldrechnungen (W. Baur, Munich), p. 168.
Elmer, O. (1982)Acta Crystalloger. B 38, 2200.
Elmer, O., and Lifson, S. (1973)J. Am. Chem. Soc. 95, 4121.
Evans, D. G., and Boeyens, J. C. A. (1988), unpublished results.
Favini, G., Rubino, C., and Todeschini, R. (1977)J. Mol. Struct. 41, 305.
Ganis, P., Lepore, U., and Martuscelli, E. (1970)J. Phys. Chem. 74, 2439.
Ganis, P., Giuliano, V., and Lepore, U. (1971)Tetrahedron Lett. 10, 765.
Gavin, R. M., Jr., and Wang, Z. F. (1973)J. Am. Chem. Soc. 95, 1425.
Goel, A. B., Goel, S., and van der Veer, D. (1982)Inorg. Chim. Acta 65, L205.
Grobbelaar, E., Kutal, C., and Orchard, S. W. (1982)Inorg. Chem. 21, 414.
Haight, H. L., Doyle, J. R., Baenziger, N. C., and Richards, C. F. (1963)Inorg. Chem. 2, 1301.
Hartley, F. R. (1973)Chem. Rev. 73, 163.
Kinoshita, I., Terai, Y. Kashiwabara, K., Kido, H., and Saito, K. (1977)J. Organomet. Chem. 127, 237.
Komiya, S., and Kochi, J. K. (1977).J. Organomet. Chem. 135, 65.
Manor, P. C., and Shoemaker, D. P., and Parkes, A. S. (1970)J. Am. Chem. Soc. 92, 5260.
Rencken, I., and Orchard, S. W. (1986)Inorg. Chem. 25, 1972.
Robin, M. B., Taylor, G. N., Kuebler, N. A., and Bach, R. D. (1973)J. Org. Chem. 38, 1049.
Robinson, D. J., and Kennard, C. H. L. (1970)J. Chem. Soc. (B), 965.
Salomon, R. G. (1983)Tetrahedron 39, 485.
Sheldrick, G. M. (1978) TheShelx 76 program system, inComputing in Crystallography, H. Schenk, R. Olthof-Hazekamp, H. Van Koningsveld, and G. C. Bassi, eds. (Delft University press, The Netherlands).
Traetteberg, M. (1975)Acta Chem. Scand, Ser, B. 29, 29.
Traynham, J. G. (1961)J. Org. Chem. 26, 4694.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rencken, I., Boeyens, J.C.A. & Orchard, S.W. Crystal structures of thetrans-cyclooctene complexes of copper(I) chloride and silver nitrate. Journal of Crystallographic and Spectroscopic Research 18, 293–306 (1988). https://doi.org/10.1007/BF01194320
Issue Date:
DOI: https://doi.org/10.1007/BF01194320