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Crystal and molecular structure of trichloro(1-methylpent-4-enylammonium)platinum(II)

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Abstract

The crystal structure of the olefinic complex of platinum(II) with 1-methylpent-4-enylammonium has been determined from single crystal X-ray data and refined by least-squares methods toR=0.049. The monoclinic crystals have unit cell dimensionsa=11.500(4),b=6.088(4),c=18.961(5) Å,β=116.92(4)°, space groupP21/c, andZ=4. In the zwitterionic complex the platinum atom is square-planar coordinated by the three chlorine atoms and by the double bond of the unsaturated ammonium cation.

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Authors and Affiliations

  1. Istituto di Strutturistica Chimica “G. Giacomello” CNR, Monterotondo St., C.P. 10, 00016, Rome, Italy

    F. Bachechi & L. Zambonelli

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  1. F. Bachechi
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  2. L. Zambonelli
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Deceased.

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Bachechi, F., Zambonelli, L. Crystal and molecular structure of trichloro(1-methylpent-4-enylammonium)platinum(II). Journal of Crystallographic and Spectroscopic Research 18, 277–284 (1988). https://doi.org/10.1007/BF01194318

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  • DOI: https://doi.org/10.1007/BF01194318

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