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Chirale Phthalid-Aromastoffe: (3a–7a)-cis-3-Butylhexahydrophthalid-Stereoisomere in Knollensellerie (Apium graveolens L var.rapaceum)

Chiral phthalid flavour compounds: stereoisomers of (3a–7a)-cis-3-butylhexahydrophthalide in celeriac (Apium graveolens L. var.rapaceum)

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Abstract

In diethyl ether extracts from celeriac (Apium graveolens L. var.rapaceum) all four stereoisomers of (3a–7a)-cis-3-butylhexahydrophthalide were found to be present. The analyses were carried out by means of GC, enantioselective GC and GC-MS. The assignment of the relative configuration of the diastereomers3 and4 was accomplished by NOE difference spectroscopy.

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Authors and Affiliations

  1. Institut für Lebensmittelwissenschaft, Eidgenössische Technische Hochschule Zürich, ETH-Zentrum, CH-8092, Zürich, Schweiz

    Giuseppe G. G. Manzardo, Sandra Kürsteiner-Laube & Daniel Perrin

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  1. Giuseppe G. G. Manzardo
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  2. Sandra Kürsteiner-Laube
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  3. Daniel Perrin
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Manzardo, G.G.G., Kürsteiner-Laube, S. & Perrin, D. Chirale Phthalid-Aromastoffe: (3a–7a)-cis-3-Butylhexahydrophthalid-Stereoisomere in Knollensellerie (Apium graveolens L var.rapaceum). Z Lebensm Unters Forch 203, 501–506 (1996). https://doi.org/10.1007/BF01193153

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  • DOI: https://doi.org/10.1007/BF01193153

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