Abstract
Coordination polymers of Cu(II), Ni(II), CO(II), Mn(II), Zn(II), oxovanadium (IV), and dioxouranium(VI) with 2-hydroxy-4-methoxyacetophenone thiourea trioxane polymer were synthesized. Elemental analyses of the coordination polymers indicate a metal-to-ligand ratio of 1:2. The diffuse reflectance spectra and magnetic moments of coordination polymers show a distorted octahedral structure. Infrared spectral studies show that the metals are coordinated through the oxygens of carbonyl and phenolic groups and the nitrogen of thioamide group. Thermal stabilities of coordination polymers were determined by thermogravimetric analysis. Semiconducting behavior of the polymer and its coordination polymers was also studied by electrical conductivity measurements at different temperatures.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
S. L. Dovydova, N. A. Plate, and V. A. Kargin,Russ. Chem. Rer. 39, 1082 (1970).
S. L. Dovydova, N. A. Plate, and V. A. Krgin,Russ. Chem. Rer. 37, 984 (1968).
D. W. Van Krevelen,Angew. Makromol. Chem. 22, 133 (1972).
R. Manavalan and M. M. Patel,J. Macromol. Sci. Chem. A 19, 951 (1983).
R. Manavalan and M. M. Patel,Makromol. Chem. 184, 717 (1983).
H. B. Pancholi and M. M. Patel,Indian J. Chem. 30A, 464 (1991).
H. B. Pancholi and M. M. Patel,High Perform. Polym. 3, 25 (1981).
M. N. Patel and S. H. Patil,J. Macromol. Sci. Chem. 19, 201 (1983).
B. J. Hathway and A. A. G. Tomilson,Coord. Chem. Res. 5, 1 (1970).
C. J. Ballhausen,Introduction to Ligand Field Theory (McGraw Hill, New York, 1962).
D. K. Rastogi and K. C. Sharma,J. Inorg. Nucl. Chem. 36, 2219 (1974).
B. Koing,Structure and Bonding, Vol. 9 (Springer, Berlin, 19XX).
A. B. P. Lever,J. Chem. Soc. A, 2041 (1967).
C. K. Jorgensen,Acta Chem. Scan. 10, 887 (1956).
R. Pappalardo,J. Chem. Phys. 31, 1052 (1959).
J. Selbin and L. Morpurgo,J. Inorg. Nucl. Chem. 27, 673 (1965).
K. Nakamoto,Infrared Spectra of Inorganic and Coordination Compounds, 2nd ed. (John Wiley. New York, 1972).
R. K. Gosavi and C. N. R. Rao,J. Inorg. Nucl. Chem. 29, 1937 (1967).
S. K. Madan and A. M. Donohue,J. Inorg. Nucl. Chem. 28, 1303 (1966).
I. S. Ahuja and R. Singh,J. Inorg. Nucl. Chem. 35, 561 (1973).
R. L. Voges, C. V. Pittman, and J. Elder,Macromolecules 4, 302 (1971).
E. C. Winslow and A. A. Manning,J. Polym. Sci. A 2, 4903 (1964).
A. Broido,J. Polym. Sci. A-2 7, 1761 (1969).
M. Spiratos, G. I. Rasu, A. Airinei, and A. Ciobanu,Angew. Makromol. Chem. 107, 33 (1982).
A. P. Terentev, V. V. Rode, E. G. Rukhadze, V. M. Vozzhennikov, Z. V. Zvonkova, and L. T. Badzhadze,Doklady Akad. Nauk SSSR 140, 1093 (1961);Chem. Abstr. 56, 9556f (1962).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Patel, M.M., Pancholi, H.B. Physicochemical properties of some new coordination polymers. J Inorg Organomet Polym 6, 51–58 (1996). https://doi.org/10.1007/BF01193012
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01193012