Skip to main content
SpringerLink
Log in

Crystal structure of chlorotriphenyltin·diphenylcyclopropenone

  • Published:
Journal of Crystallographic and Spectroscopic Research Aims and scope Submit manuscript

Abstract

Triphenyltin chloride forms with diphenylcyclopropenone a 1/1 molecular complex belonging to the triclinicP¯1 space group (a=10.267(4),b=12.095(2),c=12.319(3)Å,α=90.67(2),β=101.59(2), γ=112.58(2)°). The tin atom exists in a distortedtrans-trigonal bipyramidal (Sn-C=2.112(3), 2.123(3), 2.137(4), Sn-C1=2.440(1), Sn-O=2.510(2)Å) geometry, being displaced out of the equatorial plane (EC-Sn-C=354.3(3)°) towards the apical chlorine atom by 0.269(1)Å.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Ammon, H. L. (1973)J. Am. Chem. Soc. 95, 7093–7101.

    Google Scholar 

  • Delft Instruments (1990)MolEN structure determination system. (Delft Instruments, X-Ray Diffraction B. V., Röntgen weg 1, 2624 BD Delft, The Netherlands).

    Google Scholar 

  • Kerber, R. C., and Reis, K. P. (1989)J. Org. Chem. 54, 3550–3553.

    Google Scholar 

  • Killean, R. C. G., and Lawrence, J. L. (1969)Acta Crystallogr. B 25, 1750–1752.

    Google Scholar 

  • Kumar Das, V. G., and Ng, S. W. (1978)Malays. J. Sci. 5(B), 143–153.

    Google Scholar 

  • Kumar Das, V. G., Ng, S. W. Smith, P. J., and Hill, R. (1981)J. Chem. Soc. Dalton Trans. pp. 552–558.

  • Ng, S. W., Barnes, C. L., Hossain, M. B., van der Helm, D., Zuckerman, J. J., and Kumar Das, V. G. (1982)J. Am. Chem. Soc. 104, 5359–5364.

    Google Scholar 

  • North, A. C. T., Phillips, D. C., and Mathews, F. S. (1968)Acta Crystallogr. A 24, 351–358.

    Google Scholar 

  • Tahara, T., Imazaki, H., Aoki, K., and Yamazaki, H. (1987)J. Organomet. Chem. 327, 157–166.

    Google Scholar 

  • Tse, J. S., Lee, F. L., and Gabe, E. J. (1986)Acta Cryst. C 42, 1876–1878.

    Google Scholar 

  • Tsukada, H., Shimanouchi, H., and Sasada, Y. (1974)Chem. Lett. 639–642.

Download references

Author information

Authors and Affiliations

  1. Institute of Advanced Studies, University of Malaya, 59100, Kuala Lumpur, Malaysia

    Seik Weng Ng

  2. Department of Chemistry, University of Malaya, 59100, Kuala Lumpur, Malaysia

    V. G. Kumar Das

Authors
  1. Seik Weng Ng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. G. Kumar Das
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Weng Ng, S., Kumar Das, V.G. Crystal structure of chlorotriphenyltin·diphenylcyclopropenone. Journal of Crystallographic and Spectroscopic Research 23, 929–932 (1993). https://doi.org/10.1007/BF01185538

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01185538

Keywords

Search

Navigation