Abstract
Several optically pure representatives of 2α-hydroxy-3α-[N-alkyl (aryl)] pinanoamines, potential chiral auxiliaries in organic synthesis, were obtained. In addition, a structural examination of 2α-hydroxy-3α-(N-n-butyl)-pinanoamine hydrochloride was conducted. Results of these studies confirm the structure of the amines obtained and the correctness of the proposed reaction pathway.Crystal data: C12H28NOCl,P21/c,a=13.196(1),b=8.562(1),c=14.276(1) Å,β=110.41(3)°,R=0.034 for 2046 reflections.
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Part I,J. Cryst. Spec. Res. (1989)19, 535.
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Karolak-Wojciechowska, J., Kwiatkowski, W. & Markowicz, S.W. 2α-Hydroxy-3α-[N-alkyl(aryl)]-pinanoamines. Part II. Synthesis and the nature of some pinanoamines and crystal and molecular structure of 2α-hydroxy-3α-(N-n-butyl)-pinanoamine hydrochloride. Journal of Crystallographic and Spectroscopic Research 19, 893–903 (1989). https://doi.org/10.1007/BF01185355
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DOI: https://doi.org/10.1007/BF01185355