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Reaction of tetrahydrofuran and tetrahydropyran with trimethylbromosilane and trimethylchlorosilane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Trimethylbromosilane and trimethylchlorosilane cleaved tetrahydrofuran, giving l-bromo-4-trimethylsilyloxybutane, and correspondingly, 1-chloro-4-trimethylsilyloxybutane.

  2. 2.

    Trimethylchlorosilane cleaves the tetrahydropyran ring, from which 1-chloro-5-trimethylsilyloxypentane and polymeric products are formed.

  3. 3.

    Two product, 1,5-dibromopentane and 1-bromo-5-trimethylsilyloxypentane, are obtained by cleaving tetrahydropyran with trimethylbromosilane.

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Literature cited

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Authors and Affiliations

  1. Institute for Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    L. I. Zakharkin, V. I. Stanko & V. A. Brattsev

Authors
  1. L. I. Zakharkin
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  2. V. I. Stanko
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  3. V. A. Brattsev
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Zakharkin, L.I., Stanko, V.I. & Brattsev, V.A. Reaction of tetrahydrofuran and tetrahydropyran with trimethylbromosilane and trimethylchlorosilane. Russ Chem Bull 10, 1938–1940 (1961). https://doi.org/10.1007/BF01184741

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  • DOI: https://doi.org/10.1007/BF01184741

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