Summary
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1.
Over Raney nickel in the presence of water, the hydrogenation of the furyl ring in 1-cyclopropyl-2-α-furylcyclopropane is accompanied by its hydration without rupture of the cyclopropyl rings.
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2.
1-Cyclopropyl-2-(4′-hydroxy-1′-oxobutyl)-cyclopropane, 1-cyclopropyl-2-(4′hydroxybutyl)′-cyclopropane, 1,-cyclopropyl-2-(4′-chlorobutyl)-cyclopropane, and 1-cyclopropyl-2-butylcyclopropane have been obtained for the first time.
Literature cited
A. P. Meshceryakov, V. G. Glukhovtsev, and N. N. Lemin, Izv. AN SSSR, Otd. khim. n., 1901(1961).
Ya. M. Slobodin and I. N. Shokhor, Zh. obshch. khimii.,22, 208 (1952).
A. P. Meshcheryakov and V. G. Glukhovtsev, Izv. AN SSSR, Otd. khim. n., 1490(1959).
O. E. Curtic, I. M. Sandri, R. E. Crocker, and H. Hart, Organic Syntheses38, 19 (1958).
L. Kh. Freidlin, A. P. Meshcheryakov, V. I. Gorshkov, and V. G. Glukhovtsev, Izv. AN SSSR, Otd. khim. n., 2237(1959).
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Meshcheryakov, A.P., Glukhovtsev, V.G. Preparation of 1-cyclopropyl-2-(4′- hydroxy-1′-oxobutyd-cyclopropane. Russ Chem Bull 10, 2107–2109 (1961). https://doi.org/10.1007/BF01182969
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DOI: https://doi.org/10.1007/BF01182969