Summary
The structure of the double electrical layer has a considerable effect on the half-wave potential of the logarithmic wave of the reduction of nitrocompounds, the change in the effective potential jump exerting the main influence; the increase in the pH in the peri-electrodic layer on increasing the ionic strength of the solution has a considerably smaller effect.
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Mairanovskii, S.G., Stradyn', Y.P. Influence of the structure of the double layer on the polarographic behavior of nitro compounds. Russ Chem Bull 10, 2095–2097 (1961). https://doi.org/10.1007/BF01182964
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DOI: https://doi.org/10.1007/BF01182964