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Vinyl compounds in the diene synthesis

Communication 9. Some properties of adducts in diene condensations with vinyl sulfides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study was made of the peroxyacetic acid oxidation of the adducts formed by aryl vinyl and alkyl vinyl sulfides with hexachlorocyclopentadiene and with cyclopentadiene. The conditions were found for the preparation of sulfoxides or sulfones in high yields as main reaction products.

  2. 2.

    The adducts formed by vinyl sulfides with hexachlorocyclopentadiene are probably pure endo isomers and do not readily undergo thermal isomerization into the exo form.

  3. 3.

    When 5-(butylthio)-2-norbornene is treated with mercuric chloride solutions complex salts between different proportions of sulfide and mercuric chloride are formed.

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Literature cited

  1. M. F. Shostakovskii, A. V. Bogdanova and T. M. Ushakova, Dokl. AN SSSR118, 520 (1958); Izv. AN SSSR. Otd. khim. n. 120(1961).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    M. F. Shostakovskii, A. V. Bogdanova & T. M. Ushakova

Authors
  1. M. F. Shostakovskii
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  2. A. V. Bogdanova
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  3. T. M. Ushakova
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Shostakovskii, M.F., Bogdanova, A.V. & Ushakova, T.M. Vinyl compounds in the diene synthesis. Russ Chem Bull 10, 2073–2076 (1961). https://doi.org/10.1007/BF01182958

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  • DOI: https://doi.org/10.1007/BF01182958

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