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Thermal alkylation- of tetrahydro-2- methyl-furan with ethylene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    In the temperature range 325–375° under a pressure of ethylene of 10–50 atm there occurs the thermal alkylation of the ring of tetrahydro-2-methylfuran in the 5-position with formation of 2-ethyltetrahydro-5-methylfuran.

  2. 2.

    Under these conditions there is simultaneous partial isomerizatlon of the tetrahydro-2-methylfuran into 2-pentanone.

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Literature cited

  1. N. L. Shuikin and B. L. Lebedev, Dokl. AN SSSR 1, 131 (1961).

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  5. L. J. Bellamy, Infrared Spectra of Molecules [Russian translation] (IL, Moscow, 1957), p. 158.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    N. I. Shuikin & B. L. Lebedev

Authors
  1. N. I. Shuikin
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  2. B. L. Lebedev
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Shuikin, N.I., Lebedev, B.L. Thermal alkylation- of tetrahydro-2- methyl-furan with ethylene. Russ Chem Bull 10, 2052–2054 (1961). https://doi.org/10.1007/BF01182954

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  • DOI: https://doi.org/10.1007/BF01182954

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