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Replacement of a mercury atom attached to a saturated carbon atom by halogen

Communication 3. Reaction of benzylmercury chloride with iodine in carbon tetrachloride

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The kinetics of the reaction of benzylmercury chloride in carbon tetrachloride were studied.

  2. 2.

    The reaction is of the first order (first with respect to iodine and zero with respect to the organomereury compound).

  3. 3.

    In N,N-dimethylformamide, unlike carbon tetrachloride, the reaction mechanism is mixed. Additions of benzoyl peroxide accelerate the reaction.

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Literature cited

  1. I. P. Beletskaya, O. A. Reutov and T. P. Gur'yanova, Izv. AN SSSR. Otd. khim. n. 1589(1961).

  2. I. P. Belerskaya. O. A. Reutov and T. P. Gur'yanova, Izv. AN SSSR. Otd. khim. n. 1997(1961).

  3. Organic Solvents [in Russian] (Moscow, 1958), p. 383.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    I. P. Beletskaya, O. A. Reutov & T. P. Gur'yanova

Authors
  1. I. P. Beletskaya
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  2. O. A. Reutov
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  3. T. P. Gur'yanova
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Beletskaya, I.P., Reutov, O.A. & Gur'yanova, T.P. Replacement of a mercury atom attached to a saturated carbon atom by halogen. Russ Chem Bull 10, 2036–2039 (1961). https://doi.org/10.1007/BF01182949

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  • DOI: https://doi.org/10.1007/BF01182949

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