Summary
-
1.
The gas-phase reaction of tribromosilane with organic bromides leads to a higher molar ratio of condensation products to reduction products (C/R) than the reaction of organic bromides with trichlorosilane under the same conditions.
-
2.
The high-tempera fare reaction of mixtures of alkylchlorobenzene isomers with chlorosilanes containing siliconattached hydrogen leads to the formation of (alkylphenyl)chlorosilanes containing the same proportion of isomers in yields of 20.50%.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
A. D. Petrov. E. A. Chernyshev and Li Guan-lian, Dokl. AN SSSR137, 876 (1961).
E. A. Chernyshev and Li Guan-lian, Zh. obshch. khimii (in the press).
E. A. Chernyshev. Li Guan-lian and A. D. Petrov. Dokl. AN SSSR127, 808 (1959).
A. D. Petrov. E. A. Chernyshev and Li Guan-lian, Dokl. AN SSSR132, 1099 (1960).
E. A. Chernyshev, V. F. Mironov and A. D. Petrov, Izv. AN SSSR. Otd. km'm. n. 2147(1960).
E. A. Chernyshev, Coll. Czech Chem. Commun.25, 2161 (1960).
G. N. Mal'nova, E. P. Mikheev. A. L. Klebanskii, S. A. Golubtsov and N. P. Filimonova, Dokl. AN SSSR117, 623 (1957).
A. Barry, I. W. Gilkey, and D. E. Hook, Industt, and Engen. Chem.51, 91 (1959).
E. A. Chernyshev, V. F. Mironov, V. V. Nepomnina and S. A. Lizgunov, Zh. prikl. khimii34, 458 (1961).
M. Lerer, and C. Fabre. Bull. Soc. chirn. France, N 1, 198 (1956).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Chernyshev, E.A., Tolstikova, N.G. & Bugerenko, E.F. Gas-phase reaction of bromo- and chloro-silanes containing silicon -attached hydrogen with some organic bromo compounds and with alkylchlorobenzenes. Russ Chem Bull 10, 2032–2035 (1961). https://doi.org/10.1007/BF01182948
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01182948