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Addition of nucleophilic reagents to 2-cyanovinyl ketones

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    2-Cyanovinyl ketones readily undergo addition with nucleophilic reagents at the double bond.

  2. 2.

    The addition of the nucleophilic grouping goes in the β -position to the carbonyl group. On this basis it is concluded that the double bond in 2-cyanovinyl ketones is more strongly “conjugated with the carbonyl group and less strongly with the cyano group.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    A. N. Nesmeyanov, M. I. Rybinskaya & L. V. Rybin

Authors
  1. A. N. Nesmeyanov
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  2. M. I. Rybinskaya
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  3. L. V. Rybin
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Nesmeyanov, A.N., Rybinskaya, M.I. & Rybin, L.V. Addition of nucleophilic reagents to 2-cyanovinyl ketones. Russ Chem Bull 10, 2013–2019 (1961). https://doi.org/10.1007/BF01182944

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  • DOI: https://doi.org/10.1007/BF01182944

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