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Investigation of the reaction of electrophilic substituents on olefinic carbon atoms

3. Reaction of trans- and cis-β -chlorovinyl mercury chloride with iodine in the presence of cadmium iodide in dimethyl-formamide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The reaction of cis and trans-β-chlorovinyl mercury chloride with iodine in the presence of excess cadmium iodide in dimethylformamide was studied.

  2. 2.

    Constants for the second-order rate constant at different temperatures were determined.

  3. 3.

    The parameters of the Atrhenius equation were found.

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Literature cited

  1. L P. Beletskaya, O. A. Reutov, and V. I. Karpov, Izv. Akad. Nauk SSSR, Otd. khim. n. 1961(1961).

  2. I. P. Beletskaya, O. A. Reutov, and V.I. Karpov, Izv. Akad. Nauk SSSR, Otd. khim. n. 2125(1961).

  3. A. Welssberger, E. Proskauer, J. A. Riddick, and E. Toops, Jr., “Organic Solvents” [Russian translation] (Moscow, IL, 1958). p. 436.

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  4. I. P. Beletskaya, O. A. Reutov, and T. P. Gur'yanova, Izv. Akad. Nauk SSSR. Otd. khim. n. 1997(1961).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    I. P. Beletskaya, O. A. Reutov & V. I. Karpov

Authors
  1. I. P. Beletskaya
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  2. O. A. Reutov
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  3. V. I. Karpov
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Beletskaya, I.P., Reutov, O.A. & Karpov, V.I. Investigation of the reaction of electrophilic substituents on olefinic carbon atoms. Russ Chem Bull 10, 1989–1992 (1961). https://doi.org/10.1007/BF01182940

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  • DOI: https://doi.org/10.1007/BF01182940

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