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Investigation of the reaction of electrophilic substituents on olefinic carbon atoms

2. Reaction of trans- and cis-β-chlorovinyl mercury chloride with iodine in the presence of cadmium iodide in absolute methanol

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The reaction of cis- and trans-β-chlorovinyl mercury chloride with iodine in an excess of cadmium chloride in absolute methanol was studied.

  2. 2.

    Rate constants were determined for the second order reaction at various temperatures and the Arrhenius equation parameters were calculated.

  3. 3.

    The stereochemistry of the process was studied. Under the conditions used the reaction occurs with strict retention of geometric configuration.

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Literature cited

  1. I. P. Beletskaya, O. A. Reutov, and V. I. Karpov, Izv. Akad. Nauk SSSR, Otd. khim. n. 1961(1961).

  2. Yu. K. Yur'ev, Prakticheskie raboty po organlcheskoi khimii. Vol. II, 1957, p. 520 [in Russian].

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  4. A. N. Nesmeyanov and A. E. Borisov, Izv. Akad. Nauk SSSR, Otd. khim. n. 146(1945).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    I. P. Beletskaya, O. A. Reutov & V. I. Karpov

Authors
  1. I. P. Beletskaya
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  2. O. A. Reutov
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  3. V. I. Karpov
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Beletskaya, I.P., Reutov, O.A. & Karpov, V.I. Investigation of the reaction of electrophilic substituents on olefinic carbon atoms. Russ Chem Bull 10, 1985–1988 (1961). https://doi.org/10.1007/BF01182939

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  • DOI: https://doi.org/10.1007/BF01182939

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