Abstract
The crystal structure of the product of the reaction between [(−)Co(en)3]I3 and a mixture of Na2MoO4 and NaHC2O4 in aqueous solution is reported: [(−)Co(en)3][MoO3(C2O4)OH2]I·2H2O, space groupP212121,a=8.131(2),b=14.590(4),c=17.509(4) Å;Z=4. FinalR=0.048,R w=0.050,w=(σ 2 F)−1 for 1899 reflections. The configuration of the Mo(VI) oxalate complex differs notably from that proposed previously on the basis of chemical analysis and equilibrium studies.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Angelici, R. J. (1969)Synthesis and Techniques in Inorganic Chemistry (Saunders, London), p. 71.
Atarmyan, L. O., and Bokii, G. B. (1963)J. Struct. Chem.,4, 524.
Béltran, A., Caturla, F., Cervilla, A., and Beltran, J. (1981)J. Inorg. Nucl. Chem. 43, 3277, and references therein.
Béltran-Porter, A., Martínez-Tamayo, E., and Caturla, F. (1984)Thermochim. Acta 75, 303.
Bino, A., Cotton, F. A., and Don, Z. (1978)J. Am. Chem. Soc. 100, 5252.
Bok, L. D. C., Leipoldt, J. G., and Basson, S. S. (1972)Z. Anorg. Allg. Chem. 389, 307.
Brouty, C., Spinat, P., Whuler, A., and Herpin, P. (1976)Acta. Crystallogr. B 32, 2153.
Brouty, C., Spinat, P., and Whuler, A. (1978)Acta. Crystallogr. B 34, 425.
Brouty, C., Spinat, P., and Whuler, A. (1980)Acta. Crystallogr. B 36, 2037.
Butcher, R., and Penfold, B. R. (1976)J. Cryst. Mol. Struct. 6, 13.
Cotton, F. A., and Elder, R. C. (1964)Inorg. Chem. 3, 397.
Cotton, F. A., and Wing, R. M. (1965)Inorg. Chem. 4, 867.
Cotton, F. A., Morehouse, S. M., and Wood, J. S. (1964)Inorg. Chem. 3, 1603.
Cotton, F. A., and Morehouse, S. M. (1965)Inorg. Chem. 4, 1377.
Cromer, D. T., and Liberman, D. (1970)J. Chem. Phys. 53, 1891.
Cromer, D. T., and Mann, J. B. (1968)Acta Crystallogr. A 24, 321.
Cruywagen, J. J., and Van de Water, R. F. (1986)Polyhedron 5, 521.
Cruywagen, J. J., Heyns, J. B. B., and Van de Water, R. F. (1986)J. Chem. Soc. Dalton, 1857.
Herrmann, W., and Wieghardt, K. (1986)Polyhedron 5, 513.
Mentzen, B. F., and Sautereau, H. (1981)J. Photochem. 15, 169.
Motherwell, W. D. S. (1974) ThePluto program for molecular drawings (Cambridge University, unpublished).
Nakatsu, K. (1962)Bull. Chem. Soc. Jpn. 35, 832, and references therein.
North, A. C. T., Phillips, D. C., and Scott Matthews, F. (1968)Acta Crystallogr. A 24, 351.
Perchard, E. (1889)C.R. Acad. Sci. Paris 108, 1052.
Sheldrick, G. M. (1978) TheShelx 76 program system, inComputing in Crystallography, H. Schenk, R. Olthof-Hazekamp, H. Van Koningsveld, and G. C. Bassi, eds. (Delft University Press, The Netherlands).
Stomberg, R. (1970)Acta. Chim. Scand. 24, 2024.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Nassimbeni, L.R., Niven, M.L., Cruywagen, J.J. et al. Complexation between molybdenum(VI) and oxalate: Crystal and molecular structure of [(−)Co(en)3][MoO3(C2O4)OH2]I·2 H2O. Journal of Crystallographic and Spectroscopic Research 17, 99–107 (1987). https://doi.org/10.1007/BF01181963
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01181963