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10-Hydroxy-10-methyl-10,11-dihydroquinidine

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Abstract

10-Hydroxy-10-methyl-10,11-dihydroquinidine, C21H28N2O3,M r=365.5, crystallizes in the orthorhombic system:P212121 (No. 19),a=9.539(1),b=9.682(2),c=21.073(4) Å,Z=4,V c=1946(4) Å3,D x=1.216 g cm−3, μ(CuKα)=5.72 cm−1. The finalR=0.0346 for 1381 observed reflections. The intermolecular contacts between the hydroxyl groups and the nitrogen atoms linked each molecule to four others, with distances N⋯O 2.795(5) Å and 2.996(5) Å. Three six-membered rings in the quinuclidine moiety adopt a conformation midway between a boat and a twist boat. The geometry of theN-quinuclidine atom is compared with that from previous data.

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References

  • Duax, W. L., and Norton, D. A. (1975)Atlas of Steroid Structure (Plenum Press, New York and London).

    Google Scholar 

  • Dupont, L., Konsur, A., Lewinski, K., and Oleksyn, B. (1985)Acta Crystallogr. C 41, 616.

    Google Scholar 

  • Jaskólski, M. (1981a)Plane, program to calculate the mean plane through a set of N atoms (University of Poznań, Poland).

    Google Scholar 

  • Jaskólski, M. (1981b)Geome, program to calculate geometrical features of molecules (University of Poznań, Poland).

    Google Scholar 

  • Jaskólski, M. (1981c)Prara, program for data reduction from syntex data tapes on IBM computers (University of Poznań, Poland).

    Google Scholar 

  • Karle, I. L., and Karle, J. (1981)Proc. Natl Acad. Sci. USA 78, 5938.

    Google Scholar 

  • Kashino, A., and Haisa, M. (1983)Acta Crystallogr. C 39, 310.

    Google Scholar 

  • Lehman, M. S., and Larsen, F. K. (1974)Acta Crystallogr. A 30, 580.

    Google Scholar 

  • Main, P., Fiske, S. J., Hull, S. E., Lessinger, L., Germain, G., Declerq, J. P., and Woolfson, M. M. (1980)Multan 80, a system of computer programs for the automatic solution of crystal structures from X-ray diffraction data (Universities of York, England, and Louvain, Belgium).

    Google Scholar 

  • Oleksyn, B. J. (1982)Acta Crystallogr. B 38, 1832.

    Google Scholar 

  • Oleksyn, B. J., Stadnicka, K. M., and Hodorowicz, S. A. (1978)Acta Crystallogr. B 34, 811.

    Google Scholar 

  • Oleksyn, B., Lebioda, L., and Ciechanowicz-Rutkowska, M. (1979)Acta Crystallogr. B 35, 440.

    Google Scholar 

  • Sheldrick, G. M. (1976)Shelx 76, program for crystal structure determination (University of Cambridge, England).

    Google Scholar 

  • Suszko-Purzycka, A., Lipińska, T., Piotrowska, E., and Oleksyn, B. J. (1985)Acta Crystallogr. C 41, 977.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, Agricultural and Teachers University in Siedlce, Ul. 3, Maja 54, 08-110, Siedlce, Poland

    A. Suszko-Purzycka, T. Lipińska, Z. Karczmarzyk & B. Pniewska

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  1. A. Suszko-Purzycka
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  2. T. Lipińska
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  3. Z. Karczmarzyk
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  4. B. Pniewska
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Suszko-Purzycka, A., Lipińska, T., Karczmarzyk, Z. et al. 10-Hydroxy-10-methyl-10,11-dihydroquinidine. Journal of Crystallographic and Spectroscopic Research 17, 31–40 (1987). https://doi.org/10.1007/BF01181957

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  • DOI: https://doi.org/10.1007/BF01181957

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