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Crystal structure and infrared and electronic spectra of some divalent first series transition metal pentacyanonitrosylmanganates (I)

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Abstract

Structural and infrared and electronic spectroscopic studies of the coordination polymers corresponding to the compounds of simplest formulas M II3 [Mn(CN)5NO]2·nH2O (M=Mn, Co, Ni, Cu, Zn, andn=8–16) are reported and discussed in comparison with the corresponding nitroprussides. These polymers have a typical face centered cubic unit cell containing 1 1/3 formula units, except for M=Mn where the crystal system is orthorhombic.

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Authors and Affiliations

  1. Programa QUINOR, Quimica Inorgánica, Departamento de Quimica Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 Esquina 115, C. C. 962, 1900, La Plata, República Argentina

    D. B. Soria (Predoctoral fellow of CONICET (Consejo Nacional de Investigaciones Cientificas y Ténicas), República Argentina), L. A. Gentil (Facultad de Ingenieria, Universidad Nacional de Mar del Plata, República Argentina) & P. J. Aymonino (Member of the “Carrera del Investigador Cientifico,” CONICET, Republica Argentina)

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  1. D. B. Soria
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  2. L. A. Gentil
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  3. P. J. Aymonino
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Soria, D.B., Gentil, L.A. & Aymonino, P.J. Crystal structure and infrared and electronic spectra of some divalent first series transition metal pentacyanonitrosylmanganates (I). Journal of Crystallographic and Spectroscopic Research 18, 133–145 (1988). https://doi.org/10.1007/BF01181905

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