Abstract
CompoundA is (1α,2α,4β)-1,2-diacetoxy-4-(4-methoxyphenyl)-6-methoxy-l,2,3,4-tetrahydronaphthalene, C22H24O6,M r=384.43, monoclinic, P21/n, witha=11.074(3),b=10.353(4),c=17.616(4)Å,β=94.96(2)°,V=2012.1Å3,D calc=1.27 g cm−3 andμ=0.55 cm−1 forZ=4. Least-squares refinement of 1371 observed [F 0≥5 σ (F 0)] reflections led to the final agreement index ofR=0.052. A twofold disorder was observed for the 1-acetoxy group whereas the 2-acetoxy group was ordered. CompoundB, (1α,2α,4β)-1,2-diacetoxy-4-(2-methoxyphenyl)-8-methoxy-l,2,3,4-tetrahydronaphthalene, C22H24O6,M r=384.43, crystallizes in the monoclinic space group, P21/c, witha=16.209(2),b=10.076(1),c=13.357(4)Å,β=111.41(2)°,V=2030.9Å3,D calc=1.26 g cm−3 andμ=0.54 cm−1 forZ=4. A final agreement index ofR=0.045 was realized by least-squares refinement of 1486 observed [F o≥5 σ (F o)] reflections. Intermolecular interactions in the cell lattices of compoundsA andB are noted. The title compoundsA andB were prepared by manganese(III) acetate oxidative dimerization of two molecules of 4-methoxystyrene and 2-methoxystyrene, respectively.
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Peterson, J.R., Everson, T.P. & Rogers, R.D. Novel manganese(III) oxidation chemistry: X-ray crystal structures of (1α,2α,4β)-1,2-diacetoxy-4-(4-methoxyphenyl)-6-methoxy-1,2,3,4-tetrahydronaphthalene (compound A) and (1α,2α,4β)-1,2-diacetoxy-4-(2-methoxyphenyl)-8-methoxy-1,2,3,4-tetrahydronaphthalene (compound B). Journal of Crystallographic and Spectroscopic Research 20, 37–45 (1990). https://doi.org/10.1007/BF01181673
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DOI: https://doi.org/10.1007/BF01181673