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Conversion of spiro[4,4]nonane on platinum-alumina and palladium-alumina catalysts under catalytic reforming conditions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The conversions of spiro[4,4]nonane at 450°, a hydrogen pressure of 30 atm, a space velocity of 0.3 h−1, and a molar ratio of hydrogen to hydrocarbon of 5∶1 in the presence of 0.5% platinum-alumina and 0.5% palladium-alumina catalysts have been investigated.

  2. 2.

    In the presence of the platinum-alumina catalyst, the main conversion product is o-methylethylbenzene (41% of the catalyzate).

  3. 3.

    In the presence of the palladium-alumina catalyst isomerization of the spiro[4,4]nonane took place with the formation of indan (68% in the catalyzate).

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry Academy of Sciences of the USSR, USSR

    N. I. Shuikin & I. I. Voznesenskaya

Authors
  1. N. I. Shuikin
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  2. I. I. Voznesenskaya
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2052–2053, November, 1966.

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Shuikin, N.I., Voznesenskaya, I.I. Conversion of spiro[4,4]nonane on platinum-alumina and palladium-alumina catalysts under catalytic reforming conditions. Russ Chem Bull 15, 1994–1996 (1966). https://doi.org/10.1007/BF01179728

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  • DOI: https://doi.org/10.1007/BF01179728

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