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Remarks on donor-acceptor interaction in molecules of nitrobenzyl compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The groups YHg, CH3 and R2NCH2 in the p-derivatives of nitrobenzene have very little effect on the spectra of the nitrobenzene compounds, while the R2N group has a strong effect, and the YHgCH2 occupies an intermediate position. This relates not only to the effect of the frequency and intensity of the infrared absorption bands of the nitro group and on the first intense long-wave band in the ultraviolet spectrum, but also to the sensitivity of these parameters to the effect of intermolecular reaction. It is possible that solvation of the YHgCH2 group occurs, accompanied by an increase in its electron-donor capacity.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    P. P. Shorygin, B. V. Lopatin, M. N. Bochkareva & A. Kh. Khomenko

Authors
  1. P. P. Shorygin
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  2. B. V. Lopatin
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  3. M. N. Bochkareva
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  4. A. Kh. Khomenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2010–2012, November, 1966.

The authors wish to thank A. V. Dombrovskii and V. A Kalyavin for the graciously supplied compounds.

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Shorygin, P.P., Lopatin, B.V., Bochkareva, M.N. et al. Remarks on donor-acceptor interaction in molecules of nitrobenzyl compounds. Russ Chem Bull 15, 1940–1942 (1966). https://doi.org/10.1007/BF01179707

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  • DOI: https://doi.org/10.1007/BF01179707

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