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Mechanism of the reduction of O,O-dimethyl-2,2,2-trichloro-1-hydroxyethylphosphinate on a dropping mercury electrode

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The complete scheme of the electrode process in the reduction of O,O-dimethyl-2,2,2-trichloro-1-hydroxyethylphosphinate on a dropping mercury electrode was established.

  2. 2.

    A hypothesis was advanced on the two-step character of the electrode reaction.

  3. 3.

    The first step of the electrode reaction was characterized on the basis of the theory of irreversible waves.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences of the USSR, Kazan'

    Yu. M. Kargin & K. V. Nikonorov

Authors
  1. Yu. M. Kargin
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  2. K. V. Nikonorov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 1902–1907, November, 1966.

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Kargin, Y.M., Nikonorov, K.V. Mechanism of the reduction of O,O-dimethyl-2,2,2-trichloro-1-hydroxyethylphosphinate on a dropping mercury electrode. Russ Chem Bull 15, 1839–1844 (1966). https://doi.org/10.1007/BF01179690

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  • DOI: https://doi.org/10.1007/BF01179690

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