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Copolymerization of tri(ethylamino)boron and B-aminoborazoles with hexamethylenediisocyanate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Linear polymers containing the B-N bond were obtained by copolymerizing tri(ethylamino)boron with hexa-methylenediisocyanate; they were characterized.

  2. 2.

    New linear organoboron polymers containing a borazole ring in the main polymer chain were obtained by copolymerizing boron-substituted borazoles with hexamethylenediisocyanate; it was found that the dimethylamino group attached to boron is a catalyst for this reaction.

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Literature cited

  1. FRG patent 1,118,462, June 7, 1962; RZhKhim,1962, No. 19, 2162.

  2. British patent 854,270, November 16, 1960.

  3. V. V. Korshak, V. A. Zamyatina, N. I. Bekasova and Ma Zhuizhan, Bysokomolekul. soedineniya3, 526 (1961).

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  4. M. F. Lappert, Proc. Chem. Soc.1959, No. 2, 59.

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  5. K. Niedenzu, I. W. Dowson, J. Amer. Chem. Soc.81, 3561 (1959).

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Authors and Affiliations

  1. Institute for Heteroorganic Compounds, Academy of Sciences, USSR

    N. I. Bekasova, V. A. Zamyatina & V. V. Korshak

Authors
  1. N. I. Bekasova
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  2. V. A. Zamyatina
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  3. V. V. Korshak
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Bekasova, N.I., Zamyatina, V.A. & Korshak, V.V. Copolymerization of tri(ethylamino)boron and B-aminoborazoles with hexamethylenediisocyanate. Russ Chem Bull 13, 154–156 (1964). https://doi.org/10.1007/BF01179589

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  • DOI: https://doi.org/10.1007/BF01179589

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