Skip to main content
SpringerLink
Log in

Reaction of aluminum triisopropylate with acyl peroxides

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

Acyl peroxides react with aluminum triisopropylate at ordinary temperature with cleavage of an ester and formation of an alkoxyaluminum peracid salt which further oxidizes the isopropyl group to acetone and is converted into an alkoxyaluminum carboxylate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. V. Karnozhitskii, “Organicheskie perekisi” [in Russian] IL, Moscow., 1961, p. 37.

    Google Scholar 

  2. A. Rieche, J. Dahlmann, and D. List, Angew. Che.73, 494 (1961).

    Google Scholar 

  3. D. L. Alston, Alwyn, and G. Davies, J. Amer. Chem. Soc.84, 2465 (1962).

    Google Scholar 

  4. N. S. Vyazankin and G. A. Razuvaev et. al., Dokl. AN SSSR,143, 1348 (1962).

    Google Scholar 

  5. G. A. Razuvaev and A. I. Graevskii, Zh. obshch. khimii.32, 1006 (1962).

    Google Scholar 

  6. V. N. Latyaeva and G. A. Razuvaev, Tr. po khimii i khim. tekhnologii, Gorky, 3, 640, (1961).

    Google Scholar 

  7. A. I. Graevskii, Dissertation, In-t. vysokomolekulyamykh soedinenii SSSR, 1962, pp. 66–68.

Download references

Author information

Authors and Affiliations

  1. N. I. Lobachevskii Scientific Technical Institute, Gorky State University, USSR

    G. A. Razuvaev, L. P. Stepovik & E. V. Mitrofanova

Authors
  1. G. A. Razuvaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. P. Stepovik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Mitrofanova
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Razuvaev, G.A., Stepovik, L.P. & Mitrofanova, E.V. Reaction of aluminum triisopropylate with acyl peroxides. Russ Chem Bull 13, 142–144 (1964). https://doi.org/10.1007/BF01179584

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01179584

Keywords

Search

Navigation