Summary
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1.
The reaction of diacetylene with allylamine and diallylamine led to the formation of N-allyldiamino-1,4-butadiene-l,3 and N,N-diallylamino-l-butene-1-yne-3, respectively.
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2.
Hydration of N,N-diallylamino-1-butene-1-yne took place in the cold to formβ-(N,N-diallylamino) vinyl methyl ketone and N,N-diallylamino-1-hydroxy-3-butadiene-1,3.
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Literature cited
M. F. Shostakovskii, I. A. Chekulaeva, and L. V. Kondrat'eva, Zh. obshch. khimii30, 3179 (1960).
M. F. Shostakovskii, I. A. Chekulaeva, and L. V. Kondrat'eva, Dokl. AN SSSR146, 376 (1952).
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Kondrat'eva, L.V., Chekulaeva, I.A., Shostakovskii, M.F. et al. Addition of unsaturated amines to diacetylene. Russ Chem Bull 13, 140–141 (1964). https://doi.org/10.1007/BF01179583
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DOI: https://doi.org/10.1007/BF01179583