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Heterochain polyesters

Communication 54. Synthesis and investigation of new types of polyarylates based on 4,4'-benzylidenediphenol and 4,4'-(diphenylmethylene)diphenol

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Homogeneous and mixed polyarylates were synthesized from 4,4'-benzylidenediphenol, 4,4-(diphenylmethylene) diphenol, hydroquinone, dian, and terephthaloyl and isophthaloyl chlorides.

  2. 2.

    The question of the effect of the structures and compositions of the starting substances of the properties of the polyarylates was discussed.

  3. 3.

    Mixed polyarylates based on 4,4'-benzylidenediphenol and 4,4'-(diphenylmethylene)diphenol are distinguished by good solubility in many available organic solvents.

  4. 4.

    The presence in polyarylates of bulky phenyl side groups in the 4,4'-benzylidenediphenol and 4,4'-(diphenylmethylene) diphenol residues considerably lowers the degree of crystallinity of the polymers.

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Literature cited

  1. V. V. Korshak and S. V. Vinogradova, Uspekhi khimii30, 421 (1961).

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  2. B. M. Kovarskaya, A. S. Strizhkova, I. I. Levantovskaya, A. N. Shabadash, M. B. Neiman, V. V. Korshak, S. V. Vinogradova, and P. M. Valetskii, Vysokomolekul. soedineniya3, 432 (1962).

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  3. V. V. Korshak and S. V. Vinogradova, Izv. AN SSSR. Otd. khim. n. 636(1958).

  4. V. V. Korshak and S. V. Vinogradova, Vysokomolekul. soedineniya1, 1482 (1959).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    V. V. Korshak, S. V. Vinogradova, V. A. Pankratov & A. N. Baskakov

  2. D. I. Mendeleev Moscow Institute of Chemical Technology, USSR

    V. V. Korshak, S. V. Vinogradova, V. A. Pankratov & A. N. Baskakov

Authors
  1. V. V. Korshak
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  2. S. V. Vinogradova
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  3. V. A. Pankratov
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  4. A. N. Baskakov
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Korshak, V.V., Vinogradova, S.V., Pankratov, V.A. et al. Heterochain polyesters. Russ Chem Bull 13, 120–127 (1964). https://doi.org/10.1007/BF01179579

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  • DOI: https://doi.org/10.1007/BF01179579

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