Skip to main content
Log in

Investigation of the adsorption and ionization of oxygen by the method of triangular voltage pulses

Report 1. Adsorption and desorption of oxygen on a silver electrode during its anode and cathode polarization

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The anode and cathode behavior of silver in the potential range 0.05–2.0 V at a rate of potential change of 0.04–300 V/sec has been investigated by the method of triangular voltage pulses in a 1N KOH solution.

  2. 2.

    The potential regions at which the adsorption of hydrogen and oxygen occurs have been established.

  3. 3.

    The formation and reduction of the following oxides has been investigated by the method of triangular pulses: Ag2O, AgO, and Ag2O3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. A. N. Frumkin and A. I. Shlygin, Izv. AN SSSR, Ser. Khim., 1936, 773.

  2. G. A. Deborin and B. V. Ershler, Zh. Fiz. Khimii, 14, 708 (1940).

    Google Scholar 

  3. V. I. Nesterova and A. N. Frumkin, Zh. Fiz. Khimii, 26, 1178 (1952).

    Google Scholar 

  4. T. V. Kalish and R. Kh. Burshtein, Dokl. AN SSSR,81, 1093 (1951); Dok1. AN SSSR88, 863 (1953).

    Google Scholar 

  5. F. Will and C. A. Knorr, Z. Electrochem. 64, 258 (1960); W. Böld and M. Breiter, Electrochim. Acta 5, 145 (1961).

    Google Scholar 

  6. A. A. Rokov, Dissertation [in Russian], Moscow, 1947.

  7. V. I. Veselovskii Zh. Fiz. Khimii,13, 1543 (1939); T. I. Borisova and V.I. Veselovskii, Zh. Fiz. Khimii,27, 1195 (1953).

    Google Scholar 

  8. Yu. V. Pleskov, Dokl. AN SSSR,117, 645 (1957).

    Google Scholar 

  9. B. D. Cahan, J. B. Ockerman, R. F. Amlie, and P. Rüetschi, J. Electrochem. Soc.107, 725 (1960).

    Google Scholar 

  10. C. P. Wales and J. Burbank, J. Electrochem. Soc.106, 885 (1959).

    Google Scholar 

  11. P. Jones, H. R. Thirsk, and W. F. K. Wynne-Jones Trans. Faraday Soc.52, 1003 (1956).

    Google Scholar 

  12. T. P. Dirkse, J. Electrochem. Soc.106, 920 (1959).

    Google Scholar 

  13. K. Nagel, R. Ohse, and E. Lange, Z. Elektrochem.61, 795 (1957).

    Google Scholar 

  14. T. P. Dirkse and D. B. Vries, J. Phys. Chem.63, 107 (1959).

    Google Scholar 

  15. V. N. Alekseev, L. L. Knots, M. R. Tarasevich, and N. A. Shumilova, Zh. Fiz. Khimii, in press.

  16. A. N. Frumkin and E. A. Aikazyan, Izv. AN SSSR, Otd. Khim. N. (1959) 202.

  17. O. K. Davtyan, Dissertation [in Russian], Moscow-Erevan, 1943.

  18. P. Delahay, M. Pourbaix, and P. V. Rysselberghe, J. Electrochem. Soc.98, 65 (1951).

    Google Scholar 

  19. G. L. Vidovich, D. I. Leikis, and B. N. Kabanov, Dokl. AN SSSR124, 855 (1959); Dokl. AN SSSR142, 109 (1962).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

The article is published on the basis of a resolution of the Conference of Editors-in-Chief of the Journals of the Academy of Sciences USSR, July 12, 1962, as the dissertation work of M. R. Tarasevich.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tarasevich, M.R., Shumilova, N.A. & Burshtein, R.K. Investigation of the adsorption and ionization of oxygen by the method of triangular voltage pulses. Russ Chem Bull 13, 14–20 (1964). https://doi.org/10.1007/BF01179559

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01179559

Keywords

Navigation