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Transformation of cyclic alcohols on neodymium oxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The conversion of cyclohexanol at 200–500°, cyclopentanol and methylcyclohexanols at 350° on Nd2O3 was investigated in a circulating-type system in a stream of nitrogen.

  2. 2.

    The activation energy of the dehydration of cyclohexanol on Nd2O3 (determined without dilution with nitrogen) at 230–286° is 23.3 kcal/mole.

  3. 3.

    Cyclopentanol, cyclohexanol, and methylcyclohexanols are dehydrated to the same degree on Nd2O3 at 350° the hydrocarbon portion of the catalyzates obtained from the methylcyclohexanols containing only products of direct dehydration of the alcohols.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    Kh. M. Minachev, M. A. Markov, V. I. Bogomolov & F. É. Énglina

Authors
  1. Kh. M. Minachev
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  2. M. A. Markov
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  3. V. I. Bogomolov
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  4. F. É. Énglina
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Minachev, K.M., Markov, M.A., Bogomolov, V.I. et al. Transformation of cyclic alcohols on neodymium oxide. Russ Chem Bull 13, 10–13 (1964). https://doi.org/10.1007/BF01179558

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  • DOI: https://doi.org/10.1007/BF01179558

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