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Kinetics of the dehydrogenation and dehydration of isopropanol and dehydrogenation of tetralin on neodymium oxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The bond energies QC-cat, calculated according to the true and apparent activation energies, are close. The same also pertains to QH-cat. For QO-cat, the difference is 4.8 kcal/M.

  2. 2.

    The relative adsorption coefficients of the reaction products of the dehydrogenation and dehydration of isopropanol (except for propylene) and of the dehydrogenation of tetralin decrease with increasing temperature.

  3. 3.

    The heats of adsorption of the reaction products are greater than the heats of adsorption of isopropanol during dehydrogenation and dehydration and of tetralin during its dehydrogenation (the heat of adsorption of propylene is less than the heat of adsorption of the alcohol).

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Literature cited

  1. A. A. Tolstopyatova and A. A. Balandin, Zh. Fiz. khimii,32, 1831. (1958).

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  5. A. A. Tolstopyatova, A. A. Balandin, and P'in Pi-hsiang, Izv. AN SSSR, Otd. Khim. N., 1154 (1962).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    A. A. Tolstopyatova, A. A. Balandin & Yü Ch'i-Ch'üan

Authors
  1. A. A. Tolstopyatova
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  2. A. A. Balandin
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  3. Yü Ch'i-Ch'üan
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Tolstopyatova, A.A., Balandin, A.A. & Ch'i-Ch'üan, Y. Kinetics of the dehydrogenation and dehydration of isopropanol and dehydrogenation of tetralin on neodymium oxide. Russ Chem Bull 13, 1–5 (1964). https://doi.org/10.1007/BF01179556

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  • DOI: https://doi.org/10.1007/BF01179556

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