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Effect of high pressure on radical isomerization of 2-isopropyl-1,3-dioxolane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Pressure decreases the rate of forming ethyl isobutyrate during the homolytic liquid-phase isomerization of 2-isopropyl-1,3-dioxolane.

  2. 2.

    The volume effect for the activation of the decomposition of di-tert-butyl peroxide to 2-isopropyl-1,3-dioxolane at 130° is characterized by a substantial value (11 cm3/mole).

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    M. Ya. Botnikov, S. S. Zlotskii, V. V. Zorin, E. Kh. Kravets, V. M. Zhulin & D. L. Rakhmankulov

  2. Ufim Petroleum Institute, USSR

    M. Ya. Botnikov, S. S. Zlotskii, V. V. Zorin, E. Kh. Kravets, V. M. Zhulin & D. L. Rakhmankulov

Authors
  1. M. Ya. Botnikov
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  2. S. S. Zlotskii
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  3. V. V. Zorin
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  4. E. Kh. Kravets
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  5. V. M. Zhulin
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  6. D. L. Rakhmankulov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 690–691, March, 1977.

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Botnikov, M.Y., Zlotskii, S.S., Zorin, V.V. et al. Effect of high pressure on radical isomerization of 2-isopropyl-1,3-dioxolane. Russ Chem Bull 26, 626–628 (1977). https://doi.org/10.1007/BF01179487

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  • DOI: https://doi.org/10.1007/BF01179487

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