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Catalytic and asymmetrizing activity of mixed copper-nickel catalysts, deposited on aerosil, in the hydrogenation of acetylacetone

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A mixed Cu-Ni (1∶1) catalyst, deposited on aerosil and modified with D-(+)-tartarie acid, was obtained, which is active in theselective stereoselective hydrogenation of acetylacetone to the (-)-ketol. The optical yield of the ketol is 9.1% at 133°.

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Literature cited

  1. E. I. Klabunovskii, G. Kh. Areshidze, and A. A. Vedenyapin, Izv. Akad. Nauk SSSr, Ser Khim.,1975, 2311.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    Yu. V. Vlasenko, E. I. Klabunovskii, A. A. Vedenyapin, L. N. Brezzhunova & I. A. Rubtsov

Authors
  1. Yu. V. Vlasenko
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  2. E. I. Klabunovskii
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  3. A. A. Vedenyapin
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  4. L. N. Brezzhunova
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  5. I. A. Rubtsov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 680–682, March, 1977.

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Vlasenko, Y.V., Klabunovskii, E.I., Vedenyapin, A.A. et al. Catalytic and asymmetrizing activity of mixed copper-nickel catalysts, deposited on aerosil, in the hydrogenation of acetylacetone. Russ Chem Bull 26, 616–618 (1977). https://doi.org/10.1007/BF01179483

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  • DOI: https://doi.org/10.1007/BF01179483

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