Conclusions
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1.
The corresponding aluminum dialkyl chlorides were obtained by the reaction of aluminum trialkyls with CuSO4·2HCl at 20°.
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2.
The corresponding monoalkylaluminum dichlorides and dialkylaluminum chlorides are formed when the Gustavson complexes are reacted with a trialkylaluminum at 0–60°.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 670–672, March, 1977.
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Sangalov, Y.A., Yasman, Y.B., Minsker, K.S. et al. Synthesis of organic aluminum chloride compounds employing complex-bonded hydrogen chloride. Russ Chem Bull 26, 606–608 (1977). https://doi.org/10.1007/BF01179479
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DOI: https://doi.org/10.1007/BF01179479