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Mechanism for reaction of 1,2,3-triphenylcyclopropene with methylenedimethylsulfuran

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A mixture of the threo- and erythro-isomers of 1,4,4-trideutero-2-perdeutero(methylthiomethyl)-1,2,3-triphenyl-3-butene is formed as the result of reacting perdeuteromethylene-dimethylsulfuran with 1,2,3-triphenylcyclopropene.

  2. 2.

    The distribution of the deuterium in the obtained sulfide is in agreement with the scheme of the previously proposed mechanism of the reaction.

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Literature cited

  1. O. A. Nesmeyanova, G. A. Kudryavtseva, and O. S. Chizhov, Dokl. Akad. Nauk SSSR,210, 862 (1973).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    O. A. Nesmeyanova, G. A. Kudryavtseva, G. G. Pukitis & O. S. Chizhov

Authors
  1. O. A. Nesmeyanova
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  2. G. A. Kudryavtseva
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  3. G. G. Pukitis
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  4. O. S. Chizhov
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Additional information

Translated from Izvestlya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 663–665, March, 1977.

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Nesmeyanova, O.A., Kudryavtseva, G.A., Pukitis, G.G. et al. Mechanism for reaction of 1,2,3-triphenylcyclopropene with methylenedimethylsulfuran. Russ Chem Bull 26, 599–601 (1977). https://doi.org/10.1007/BF01179476

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  • DOI: https://doi.org/10.1007/BF01179476

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