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Formation of monomeric α-butylthioacrolein and its unusual reaction with 2,4-dinitrophenylhydrazine

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reaction of butylthioacetaldehyde with formaldehyde and diethylamine hydrochloride in neutral medium at 6–10° leads to the formation of the unstable α-butylacrolein. Treatment of the latter with 2,4-dinitrophenylhydrazine gives the 2,4-dinitrophenylhydrazone of acetone.

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Literature cited

  1. N. A. Keiko and L. G. Stepanova, Izv. Akad. Nauk SSSR, Ser. Khim., 2516 (1972).

  2. I. Heilbron and G. M. Banbury, Dictonary of Organic Compounds [Russian translation] Vol. 1, IL (1949), p. 13.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    N. A. Keiko, L. G. Stepanova, I. D. Kalikhman & M. G. Voronkov

Authors
  1. N. A. Keiko
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  2. L. G. Stepanova
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  3. I. D. Kalikhman
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  4. M. G. Voronkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 659–660, March, 1977.

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Keiko, N.A., Stepanova, L.G., Kalikhman, I.D. et al. Formation of monomeric α-butylthioacrolein and its unusual reaction with 2,4-dinitrophenylhydrazine. Russ Chem Bull 26, 595–596 (1977). https://doi.org/10.1007/BF01179474

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  • DOI: https://doi.org/10.1007/BF01179474

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