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Asymmetric nonbridgehead nitrogen

11. Derivatives of 1-alkoxyaziridine-2,2-dicarboxylic acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have synthesized 1-alkoxyaziridine-2,2-dicarboxylic esters by reaction of alkoxyamines with diethyl α,β-dibromomethylmalonate and studied their PMR and mass spectra.

  2. 2.

    We have established the trans-stereospecificity of the amination and saponification of l-alkoxyaziridine-2,2-dicarboxylic esters.

  3. 3.

    We have studied the kinetics of the equilibrium cis-trans isomerization of unsymmetrically substituted derivatives of 1-alkoxyaziridine-2,2-dicarboxylic acids.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    R. G. Kostyanovskii, V. F. Rudchenko & A. V. Prosyanik

Authors
  1. R. G. Kostyanovskii
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  2. V. F. Rudchenko
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  3. A. V. Prosyanik
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Additional information

For Part 10, see [1].

Translated from Izvestiya Akademiya Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 628–638., March, 1977.

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Kostyanovskii, R.G., Rudchenko, V.F. & Prosyanik, A.V. Asymmetric nonbridgehead nitrogen. Russ Chem Bull 26, 565–574 (1977). https://doi.org/10.1007/BF01179468

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  • DOI: https://doi.org/10.1007/BF01179468

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