Skip to main content
SpringerLink
Log in

Carbonylation of iodoalkanes by carbon monoxide in alcoholic media in the presence of a zeolite RhNaX catalyst

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Zeolite RhNaX is an active catalyst for the carbonylation of alkyl iodides in media containing aliphatic alcohols into esters of the corresponding carboxylic acids at 200 to 250°C and a CO pressure of 1 to 100 atm.

  2. 2.

    Increasing the CO pressure to 100 atm sharply increases the rate of the carbonylation and suppresses the secondary reactions.

  3. 3.

    The reactivity of iodoalkanes decreases as their molecular weight is increased.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. B. K. Nefedov, N. S. Sergeeva, T. V. Zueva, E. M. Shutkina, and Ya. T. Éidus, Izv. Akad. Nauk SSSR, Ser. Khim., 582 (1976).

  2. B. K. Nefedov, N. S. Sergeeva, and Ya. T. Éidus, Izv. Akad. Nauk SSSR, Ser. Khim., 2271 (1976).

  3. F. E. Paulick, A. Hershman, J. F. Roth, J. H. Craddock, W. R. Knox, and R. G. Schultz, South African Patent No. 6802174 (1968); Chem. Abstrs.,71, 12573 (1969).

    Google Scholar 

  4. S. M. Brailovskii, O. N. Temkin, and V. A. Khalif, “Catalytic reactions in the liquid phase,” in:Proceedings of the Fourth All-Union Conference on Liquid-Phase Catalytic Reactions [in Russian], Part III, Alma-Ata (1974), p. 631.

  5. K. K. Robinson, A. Hershman, J. H. Craddock, and J. F. Roth, J. Catal.,27, 389 (1972).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    B. K. Nefedov, N. S. Sergeeva & L. L. Krasnova

Authors
  1. B. K. Nefedov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. S. Sergeeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. L. Krasnova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 614–620, March, 1977.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nefedov, B.K., Sergeeva, N.S. & Krasnova, L.L. Carbonylation of iodoalkanes by carbon monoxide in alcoholic media in the presence of a zeolite RhNaX catalyst. Russ Chem Bull 26, 552–557 (1977). https://doi.org/10.1007/BF01179465

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01179465

Keywords

Search

Navigation