Conclusions
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1.
Each of the aryl methyl disulfides exists in skew conformation with a C-S-S-C dihedral angle of 70–90°.
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2.
The angle of rotation of the p-XC6H4, fragment relative to the plane of the Car-S-S bonds varies from molecule to molecule, depending on the nature of the X substituent.
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S. G. Vul'fson, L. A. Sorokina, L. M. Kataeva, A. N. Vereshchagin, and E. G. Kataev, Dokl. Akad. Nauk SSSR,219, 1363 (1974).
S. G. Vul'fson, L. A. Sorokina, L. M. Kataeva, and A. N. Vereshchagin, Dokl. Akad. Nauk SSSR,216, 837 (1974).
M. J. Aroney, R. J. W. Le Fevre, R. K. Pierens, and H. L. K. The, Austr. J. Chem.,21, 281 (1968).
E. L. Eliel et al., Conformational Analysis [Russian translation], Mir (1969), p. 528.
S. G. Vul'fson, G. Ya. Cheryukanova, G. A. Chmutova, and A. N. Vereshchagin, Dokl. Akad Nauk SSSR,212, 621 (1973).
K. S. Boustany and A. B. Sullivan, Tetrahedron Lett., 3547 (1970).
D. A. Armitage, M. J. Clark, and C. C. Tso, J. Chem. Soc. Perkin Trans.,1972, 680.
A. N. Vereshchagin and L. A. Grozina, Teor. Eksp. Khim.,4, 361 (1968).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 607–610, March, 1977.
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Sorokina, L.A., Kataeva, L.M., Vul'fson, S.G. et al. Polarizations, polarizabilities, and conformations of the aryl methyl disulfides. Russ Chem Bull 26, 545–548 (1977). https://doi.org/10.1007/BF01179463
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DOI: https://doi.org/10.1007/BF01179463