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Polarographic study of aliphatic nitro compounds

8. Mechanism of the reduction of the un-ionized forms of dinitroethane and fluorodinitromethane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Study bas shown that the first stage in the reduction of 1,1-dinitroethane and fluorodinitromethane in strongly acidic solution is a two-electron C-N bond rupture process, the subsequent stages of the reaction being determined by the relative rates of the competing processes of protonation, nitrosation, and Neff reaction.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. V. Paramonov, V. A. Petrosyan & V. I. Slovetskii

Authors
  1. V. V. Paramonov
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  2. V. A. Petrosyan
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  3. V. I. Slovetskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 567–573, March, 1977.

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Paramonov, V.V., Petrosyan, V.A. & Slovetskii, V.I. Polarographic study of aliphatic nitro compounds. Russ Chem Bull 26, 509–514 (1977). https://doi.org/10.1007/BF01179455

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  • DOI: https://doi.org/10.1007/BF01179455

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