Skip to main content
SpringerLink
Log in

A spin-trap ESR study of the regrouping of radicals with 1,3 or 1,5 hydrogen migration

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Spin-trap (2-methyl-2-nitrosopropane) ESR methods have been used to demonstrate the formation of R1O2CĊR2CH2CH2C6H13 (R1=H, CH3 and R2=Cl, CH3) radicals during the photoinitiated reaction (λ ∼ 2537 Å) of 1-octene with BrCHClCOOH and CH3CHBrCOOCH3 in the presence of tert-outyl peroxide and (C3H5)3SiH. Formation of these radicals indicates regrouping of the R1O2CCHR2CH2ĊHC6H13 radical with 1,3 H atom migraion and, possibly, regrouping of the R1O2CCHR2CH2CH(C6H13)CH2CHC6H13 radical with 1,5 H atom migration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. B. Terent'ey, N. S. Ikonnikov, V. I. Dostovalova, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,213, 1345 (1973).

    Google Scholar 

  2. A. B. Terent'ey, M. A. Churilova, N. S. Ikonnikov, and R. Kh. Freidiina, Izv. Akad. Nauk SSSR, Ser. Khim., 439 (1975).

  3. A. B. Terent'ev, M. A. Churilova, and D. I. Povoiotskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2497 (1975).

  4. N. S. Ikonnikov, A. B. Terent'ev, M. A. Churilova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 2479 (1972).

  5. G. R. Chalfont, M. J. Perkins, and A. Horsfield, J. Am. Chem. Soc.,90, 7141 (1968).

    Google Scholar 

  6. R. G. Gasanov, I. I. Kandror, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,226, 342 (1976).

    Google Scholar 

  7. A. Mackor, Th. A. J. W. Wajer, and Th. J. de Boer, Tetrahedron,24, 1623 (1968).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    R. G. Gasanov, A. B. Terent'ev & R. Kh. Freidlina

Authors
  1. R. G. Gasanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. B. Terent'ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. Kh. Freidlina
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 545–549, March, 1977.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gasanov, R.G., Terent'ev, A.B. & Freidlina, R.K. A spin-trap ESR study of the regrouping of radicals with 1,3 or 1,5 hydrogen migration. Russ Chem Bull 26, 489–493 (1977). https://doi.org/10.1007/BF01179450

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01179450

Keywords

Search

Navigation