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Mechanism of oxidational dehydrogenation of ethylbenzene on an aluminum oxide catalyst

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Styrene formation in the oxidational dehydrogenation of ethylbenzene on an aluminum oxide catalyst is directly from the ethylbenzene through an earlier proposed mechanism, rather than from intermediate condensation products through a consecutive mechanism.

  2. 2.

    The condensation products imply function as catalysts for styrene formation, their activity in this reaction being higher than that of the aluminum oxide itself.

  3. 3.

    Carbon dioxide is formed through combustion of the condensation products, rather than from ethylbenzene and styrene.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. I. Kozharov, L. A. Makhlis, A. E. Lisovskii, T. G. Alkhazov & B. E. Vasserberg

  2. M. Azizbekov Azerbaidzhan Institute of Petroleum and Chemistry, Baku

    A. I. Kozharov, L. A. Makhlis, A. E. Lisovskii, T. G. Alkhazov & B. E. Vasserberg

Authors
  1. A. I. Kozharov
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  2. L. A. Makhlis
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  3. A. E. Lisovskii
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  4. T. G. Alkhazov
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  5. B. E. Vasserberg
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 532–535, March, 1977.

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Kozharov, A.I., Makhlis, L.A., Lisovskii, A.E. et al. Mechanism of oxidational dehydrogenation of ethylbenzene on an aluminum oxide catalyst. Russ Chem Bull 26, 477–480 (1977). https://doi.org/10.1007/BF01179446

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  • DOI: https://doi.org/10.1007/BF01179446

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